描述
Poly
有机光电子聚合物给体材料PM6, PBDB-T-2F, PBDB-TF, PCE 20%+
Catalog No.: P9203
Molecular formula: (
CAS No.: 1802013-83-7 ; CAS No.: 1802013-84-8 (from 2 monomers)
Other Names for this Substance:
- PBDB-T-2F
- PBDB-TF
- PM6
- PM 6
HOMO level: -5.45 eV
LUMO level: -3.60 eV
热门的有机太阳能电池给体材料。
我们提供两种品质的PM6:
标准批次的PM6与Y6制备器件的PCE>16%; (相同批次与IT-4F器件结果13.5%左右)
高品质批次的PM6与Y6制备器件的PCE在17%水平。可用于冲击有机太阳能电池高效率。(相同批次与IT-4F器件结果13.8%以上,部分批次超过14%,数量较少)
Structure: ITO/PEDOT:PSS/PBDB-T-2F+BTP-eC9/PDINO/Al
Reported:
Voc=0.839V, Jsc=26.20mA/cm2, FF=81.10%, PCE=17.80%
Adv Mater, 2020, 32: 1908205
1: A Large-Bandgap Conjugated Polymer for Versatile Photovoltaic Applications with High Performance; Advanced Materials (2015), 27(31), 4655-4660
Herein, we synthesized a new copolymer PM6 based on 4,8-bis(5-(2-ethylhexyl)-4-fluorothiophen-2-yl)benzo[1,2-b:4,5-b’]dithiophene(BDT-F) and 1,3-bis(thiophen-2-yl)-5,7-bis(2-ethylhexyl)benzo-[1,2-c:4,5-c’]dithiophene-4,8-dione (BDD). The optical, electrochem., and photovoltaic properties, the mol. packing pattern, and the morphol. of the blend lms were investigated. Compared with the nonfluorinated derivative PBDTBDD, PM6 exhibited a similar optical bandgap of 1.80 eV and a deeper HOMO level of -5.45 eV (-5.25 eV for PBDTBDD), which is beneficial for a high Voc. BHJ PSCs based on PM6/PC71 BM with both conventional and inverted device structures were fabricated and showed promising photovoltaic performance: a high Voc of 0.98 V and a PCE of 8% for the conventional devices and up to 9.2% for the inverted devices. Furthermore, the PM6/PC71BM based semitransparent device exhibited a PCE of 5.7%, which is among the highest values obtained for a semitransparent single-junction device. In addition, we found that the neat film of PM6 exhibited strong crystallinity and a dominant face on packing with respect to the electrodes, which is advantageous for charge transport. These results indicate that PM6 is a promising material for photovoltaic application.
2: 19.31% binary organic solar cell and low non-radiative recombination enabled by non-monotonic intermediate state transition; Nature Communications (2023), 14(1), 1760
3: Approaching 19% efficiency and stable binary polymer solar cells enabled by a solidification strategy of solvent additive; Science China: Chemistry (2023), 66(5), 1500-1510
4: High-Efficiency Binary Organic Solar Cells Enabled by Pseudo-Bilayer Configuration in Dilute Solution; Solar RRL (2023), 7(9), 2201090
5: High-performance and mechanically durable semi-transparent organic solar cells with highly transparent active layers; Science China Materials (2023), 66(5), 1719-1726
6: Over 18% efficiency ternary all-polymer solar cells with high photocurrent and fill factor; Matter (2023), 6(5), 1542-1554
7: Halogen-Free Donor Polymers Based on Dicyanobenzotriazole with Low Energy Loss and High Efficiency in Organic Solar Cells; Small (2023), 19(18), 2206607
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